Effective Carbon/TiO(2) Gel for Enhanced Adsorption and Demonstrable Visible Light Driven Photocatalytic Performance

高效碳/TiO₂凝胶可增强吸附性能并展现出可见光驱动的光催化性能

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Abstract

A new strategy to synthesise carbon/TiO(2) gel by a sol-gel method is proposed. Textural, morphological, and chemical properties were characterised in detail and the synthesised material was proven to be an active adsorbent, as well as a visible light photocatalyst. Homogenously distributed TiO(2) is mesoporous with high surface area and, hence, exhibited a high adsorption capacity. The adsorption equilibrium experimental data were well explained by the Sips isotherm model. Kinetic experiments demonstrated that experimental data fitted a pseudo second order model. The modification in electronic structure of TiO(2) resulted in a reduced bandgap compared to commercial P25. The absorption edge studied through UV-Vis shifted to the visible region, hence, daylight photocatalytic activity was efficient against degradation of MB dye, as an example pollutant molecule. The material was easily removed post treatment, demonstrating potential for employment in industrial water treatment processes.

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