Using 3-Isocyanatopropyltrimethoxysilane to Decorate Graphene Oxide with Nano-Titanium Dioxide for Enhancing the Anti-Corrosion Properties of Epoxy Coating

利用3-异氰酸丙基三甲氧基硅烷修饰氧化石墨烯并负载纳米二氧化钛以增强环氧涂层的抗腐蚀性能

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Abstract

In this paper, the graphene oxide loaded with nano titanium dioxide (TiO(2)-GO) was synthesized through 3-isocyanatopropyltrimethoxysilane (IPTMS) and characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and dispersion test. The results illustrated our modification was successful and TiO(2)-GO was transferred from hydrophilic to hydrophobic. That greatly enhanced the dispersity of TiO(2)-GO in epoxy through the observation of the coating morphology test. Moreover, the impact of TiO(2)-GO on anti-corrosion property in epoxy was investigated by Electrochemical Impedance Spectroscopy (EIS). Comparing to pristine particles including GO and TiO(2), TiO(2)-GO could more significantly improve the resistance of corrosion with the help of IPTMS. Furthermore, the anti-corrosion mechanism of TiO(2)-GO in epoxy was tentatively proposed and discussed.

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