Synthesis of porphyrin-dendrimers with a pyrene in the periphery and their cubic nonlinear optical properties

外围带有芘基团的卟啉树状大分子的合成及其立方非线性光学性质

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Abstract

Dendrons of pyrene derivatives were attached to a porphyrin core. A marked effect in solution for the dendrimers was observed in the absorption spectra. All the compounds obtained were characterized by (1)H-, (13)C-NMR, FTIR, UV-vis, MALDI-TOF or FAB+ mass spectrometry and elemental analysis. The cubic nonlinear optical behavior of some the synthesized compounds was tested via Z-Scan measurements in spin-coated film samples.

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