One-Step Construction of Multi-Walled CNTs Loaded with Alpha-Fe(2)O(3) Nanoparticles for Efficient Photocatalytic Properties

一步法构建负载α-Fe₂O₃纳米粒子的多壁碳纳米管及其高效光催化性能

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Abstract

The aggregation and the rapid restructuring of the photoinduced electron-hole pairs restructuring in the process of photoelectric response remains a great challenge. In this study, a kind of Multi-walled carbon nanotubes loaded Alpha-Fe(2)O(3) (CNTs/α-Fe(2)O(3)) heterostructure composite is successfully prepared via the one-step method. Due to the synergistic effect in the as-prepared CNTs/α-Fe(2)O(3), the defect sites and oxygen-containing functional groups of CNTs can dramatically improve the interface charge separation efficiency and prevent the aggregation of α-Fe(2)O(3). The improved photocurrent and enhanced hole-electron separation rate in the CNTs/α-Fe(2)O(3) is obtained, and the narrower band gap is measured to be 2.8 ev with intensive visible-light absorption performance. Thus, the CNTs/α-Fe(2)O(3) composite serves as an excellent visible light photocatalyst and exhibits an outstanding photocatalytic activity for the cationic dye degradation of rhodamine B (RhB). This research supplies a fresh application area forα-Fe(2)O(3) photocatalyst and initiates a new approach for design of high efficiency photocatalytic materials.

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