Bis[2-(1,3-benzo-thia-zol-2-yl)phenyl-κ(2) C (1),N][1,3-bis-(4-bromo-phen-yl)propane-1,3-dionato-κ(2) O,O']iridium(III)

双[2-(1,3-苯并-噻唑-2-基)苯基-κ(2) C (1),N][1,3-双-(4-溴-苯基-基)丙烷-1,3-二酮-κ(2) O,O']铱(III)

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作者:Young-Inn Kim, Seong-Jae Yun, Sung Kwon Kang

Abstract

The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the Ir(III) atom and the central C atom of the bis-(bromo-phen-yl)propane-1,3-dionate ligand. The Ir(III) atom adopts a distorted octa-hedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thia-zole ring systems in the complex is 77.45 (10)°.

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