Plasma surface-modification of cellulose nanocrystals: a green alternative towards mechanical reinforcement of ABS

纤维素纳米晶体的等离子体表面改性:一种用于增强ABS机械性能的绿色替代方案

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Abstract

This article proposes a strategy to functionalize cellulose nanocrystals by means of plasma-surface modification utilizing monomers of different nature: caprolactone, styrene and farnesene. The surface characteristics of the nanocrystals were studied by different techniques including XPS, FTIR and STEM, demonstrating that this technique allows a successful functionalization, yielding homogenous functionalization which does not alter the rod-like shape of the nanocrystals, and therefore their anisotropic behavior. We have furthermore studied the employment of the modified nanocrystals as reinforcement additive of ABS, which significantly enhanced the impact resistance of the thermoplastic, which could have great implications for industrial applications.

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