One-pot green bio-assisted synthesis of highly active catalytic palladium nanoparticles in porcine gastric mucin for environmental applications

猪胃粘蛋白中高活性催化钯纳米粒子的一锅绿色生物辅助合成及其环境应用

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作者:Roman Nudelman, Shir Zuarets, Meiron Lev, Shira Gavriely, Louisa Meshi, Ines Zucker, Shachar Richter

Abstract

In this work, palladium nanoparticles were synthesized using one-pot synthesis utilizing porcine gastric mucin glycoproteins as reducing and capping agents. It is shown that the particles exhibited noticeable catalytic activity through both nitrophenol reduction and Suzuki-Miyaura coupling reactions. The catalytic performance was demonstrated with exceptionally high product yield, a fast reaction rate, and low catalyst use. The palladium-mucin composites obtained could be used in particle solution and as hydrogel catalysts to increase their reusability for at least ten reaction cycles with minimum loss in their catalytic effectiveness.

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