Abstract
Fluorescent fibers are capable of discoloration behavior under special light sources, showing great potential for applications in biomedicine, environmental monitoring, heavy-metal-ion detaction, and anti-counterfeiting. In the current paper, temperature-sensitive fluorescent poly-acrylamide (PAM) nanofiber (AuNCs@PAM NF) membranes are prepared by mixing red fluorescent gold nanoclusters (AuNCs) synthesized in-house with PAM using the electrospinning technique. The AuNCs@PAM nanofibers obtained using this method present excellent morphology, and the AuNCs are uniformly dispersed in the fibers. The average diameter of the AuNCs@PAM NFs is 298 nm, and the diameter of AuNCs doped in the fibers is approximately 2.1 nm. Furthermore, the AuNCs@PAM NF films present excellent fluorescence and temperature-sensitive performance between 15 and 65 degrees. While under the 365 nm UV light source, the fiber film changes from white to red; this discoloration behavior weakens with the increase in temperature, and changes from deep to light red. Therefore, the approximate temperature can be identified using the color change, and a visual temperature-sensing effect can be achieved. The dual functions of temperature-sensitivity and fluorescent properties improve the scientificity and safety of nanofibers in the use of anti-counterfeiting technology.