Weak exciton scattering in molecular nanotubes revealed by double-quantum two-dimensional electronic spectroscopy

双量子二维电子光谱揭示分子纳米管中的弱激子散射

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Abstract

The two-exciton manifold of a double-wall cylindrical molecular aggregate is studied using a coherent third order optical technique. Experiments reveal the anharmonic character of the exciton bands. Atomistic simulations of the exciton-exciton scattering show that the excitons can be treated as weakly coupled hard-core bosons. The weak coupling stems from the extended exciton delocalization made possible by the nanotube geometry.

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