Functional group compatibility. Propargyl alcohol reduction in the presence of a vinyl iodide

官能团相容性。在碘乙烯存在下炔丙醇的还原

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Abstract

Vinyl iodides are stable to the reduction of propargyl alcohols to cis allylic alcohols by hydrogen over Pd/CaCO(3) in hexane. They are also stable to the reduction of propargyl alcohols to saturated alcohols by hydrogen over Crabtree's iridium catalyst in CH(2)Cl(2).

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