An In-Situ Fabrication Method of ZnO and Other Zn(II) Compounds Containing Polypropylene Composites

一种含 ZnO 和其他 Zn(II) 化合物的聚丙烯复合材料的原位制备方法

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作者:Katarzyna Kupińska, Maciej Michalik, Justyna Krajenta, Magda Bielicka, Karolina Halina Markiewicz, Beata Kalska-Szostko, Agnieszka Zofia Wilczewska

Abstract

This study investigated the methods of preparation of zinc oxide-polypropylene nanocomposites and their antibacterial properties. Seven solutions with ZnO nanoparticles or zinc ions were formulated as a PP additive. Two methods of ZnO NPs syntheses were carried out: (1) a modified hydrothermal method where a water solution of zinc acetate dihydrate, PEI, and ammonia were mixed with a final pH 11; (2) a thermal decomposition of a water solution of zinc acetate in the presence of PEI and ammonia using a two-screw extruder. During the experiments, the influence of various amounts of particle stabilizer, heating of the solutions, and the temperatures of the syntheses were examined. As a result, the simultaneous crystallization of ZnO in the extrusion process confirmed this method's attractiveness from the application point of view. Fabricated PP-ZnO composite shows antibacterial properties against Staphylococcus aureus, Escherichia coli, and Klebsiella pneumoniae.

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