Abstract
Integral cross sections and rate constants for the prototypical chemical reactions of the fluorine atom with molecular hydrogen and deuterium have been calculated over a wide interval of collision energy and temperature ranging from the sub-thermal (50 K) down to the ultra-cold regimes (0.5 mK). Rigorous close coupling time-independent quantum reactive scattering calculations have been carried out on two potential energy surfaces, differing only at long-range in the reactants' channel. The results show that tunnel, resonance and virtual state effects enhance under-barrier reactivity giving rise to pronounced deviations from the Arrhenius law as temperature is lowered. Within the ultra-cold domain (below 1 mK), the reactivity is governed by virtual state effects and by tunneling through the reaction barrier; in the cold regime (1 mK-1 K), the shape resonances in the entrance channel of the potential energy surface make the quantum tunneling contribution larger so enhancing cross sections and rate constants by about one order of magnitude; at higher temperatures (above 10 K), the tunneling pathway enhanced by the constructive interference between two Feshbach resonances trapped in the reaction exit channel competes with the thermally activated mechanism, as the energy gets closer to the reaction barrier height. The results show that at low temperatures cross sections and rate constants are extremely sensitive to small changes in the long-range intermolecular interaction in the entrance channel of the potential energy surface, as well as to isotopic substitution.