Flexible and high energy density solid-state asymmetric supercapacitor based on polythiophene nanocomposites and charcoal

基于聚噻吩纳米复合材料和活性炭的柔性高能量密度固态非对称超级电容器

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Abstract

An asymmetric supercapacitor (ASC) was constructed using a polythiophene/aluminium oxide (PTHA) nanocomposite as an anode electrode and charcoal as a cathode electrode. The highest specific capacitance (C (sp)) of the PTHA electrode was found to be 554.03 F g(-1) at a current density (CD) of 1 A g(-1) and that of the charcoal electrode was 374.71 F g(-1) at 1.4 A g(-1), measured using a three electrode system. The maximum C (sp) obtained for the assembled PTHA//charcoal asymmetric supercapacitor (ASC) was 265.14 F g(-1) at 2 A g(-1). It also showed a high energy density of 42.0 W h kg(-1) at a power density of 735.86 W kg(-1) and capacitance retention of 94.61% even after 2000 cycles. Moreover, it is worth mentioning that the asymmetric device was used to illuminate a light emitting diode (LED) for more than 15 minutes. This PTHA//charcoal ASC also possesses stable electrochemical properties in different bending positions and hence finds a promising application in flexible, wearable and portable energy storage electronic devices.

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