Facile Synthesis of Mesoporous Carbon Spheres Using 3D Cubic Fe-KIT-6 by CVD Technique for the Application of Active Electrode Materials in Supercapacitors

利用CVD技术以3D立方Fe-KIT-6为催化剂简便合成介孔碳球,并将其应用于超级电容器活性电极材料

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Abstract

Mesoporous carbon spheres (MCS-750, MCS-800, MCS-850, MCS-900, and MCS-950) have been synthesized by a facile strategy with low temperature and rapid chemical vapor deposition technique. The synthesized MCS possess relatively large surface area (570-670 m(2) g(-1)), good graphitization, remarkable porosity, and redox functionalities on the surface of the synthesized MCS. Combination of these structural and surface properties of the synthesized MCS as an electrode material (MCS-850) showed an excellent charge-storage capacity with a specific capacitance of 338 F/g at 1 mV/s, 217 F/g at 0.5 A/g. MCS-850 shows long-term cycling stability with capacitive retention of more than 96% after 2000 cycles in 6 M KOH electrolyte. In addition, a fabricated two-electrode symmetric cell obtained 86% retention after 2000 cycles. The two-electrode symmetric device exhibited a specific capacitance of 63 F/g at 5 mV/s with an energy density of 7.1 Wh/kg.

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