Investigation of the Bonding Performance and Microstructure of MOC Binders for SiO(2) as Rock-like Composites

研究MOC粘结剂对SiO(2)作为岩石状复合材料的粘结性能和微观结构的影响

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Abstract

The heterogeneity of natural rocks complicates the study of carbon sequestration within these materials and raises concerns about the reproducibility of experimental results. Consequently, identifying appropriate rock-like materials has become critical. This research examined the impact of various factors-humidity, binder content, curing period, and cold pressure-on the bond strength of magnesium oxychloride cement (MOC) through orthogonal testing. The tests utilized a molar ratio of MgO to MgCl(2)-6H(2)O to H(2)O of 7:1:18. Both X-ray diffraction (XRD) and scanning electron microscopy (SEM) were employed to analyze the hydration reactions of MOC and to explore the correlation between the microstructure of the SiO(2)-MgO-MgCl(2) system and its bonding characteristics. The findings indicated that a 5% relative humidity enhances the 7-day bond strength of MOC. Moreover, increasing the curing humidity to 60% relative humidity supports the ongoing hydration of the strength-contributing phases. A binder content ranging from 15% to 25% proved optimal, yielding samples with superior strength and stiffness. While cold pressing initially enhances the bonding properties of MOC, solution loss during the process adversely affects its long-term bonding characteristics. From a mechanical standpoint, the silica-magnesium oxide-magnesium chloride system demonstrates exceptional early strength and resilience, positioning it as a promising rock-like material system.

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