Bioinspired triangular ZnO nanoclusters synthesized by Argyreia nervosa nascent leaf extract for the efficient electrochemical determination of vitamin C

受生物启发,由银叶菊新生叶提取物合成的三角形 ZnO 纳米簇可用于高效电化学测定维生素 C

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作者:Pooja Singh, Kshitij Rb Singh, Jay Singh, Priyanka Prasad, Ravindra Pratap Singh

Abstract

This work deals with the synthesis of bioinspired triangular ZnO nanoclusters (bT-ZnO NCs) from Argyreia nervosa nascent leaf extract for their effective antibacterial activity and further utilization as a platform for the electrocatalytic determination of ascorbic acid (AA; vitamin C) for applications in the agricultural domain. The structural, optical, and morphological characteristics of the synthesized bT-ZnO NCs were analyzed by UV-vis, FT-IR, XRD, AFM, SEM, TEM, HR-TEM, and EDX techniques. After this, bT-ZnO NCs were electrophoretically deposited onto an indium-tin-oxide (ITO) glass substrate and assessed for the electro-oxidation of AA by cyclic voltammetry (CV), and from this it was proven that bT-ZnO NCs had a very high electrochemical sensitivity of 29.88 μA cm-2 toward AA and a low limit of detection of 0.5321 mM under the optimized experimental conditions. Thus, it provides a potential sensing platform for electrochemical studies to detect AA. Moreover, bT-ZnO NCs were preliminarily investigated for their antibacterial activity, and the obtained results showed that the bT-ZnO NCs have potency as an antibacterial agent.

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