Synthesis, Characterization and Mechanical Properties of Novel Bio-Based Polyurethane Foams Using Cellulose-Derived Polyol for Chain Extension and Cellulose Citrate as a Thickener Additive

使用纤维素衍生多元醇进行链扩展并使用纤维素柠檬酸酯作为增稠剂的新型生物基聚氨酯泡沫的合成、表征和机械性能

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作者:Loredana Maiuolo, Fabrizio Olivito, Vincenzo Algieri, Paola Costanzo, Antonio Jiritano, Matteo Antonio Tallarida, Antonio Tursi, Corradino Sposato, Andrea Feo, Antonio De Nino

Abstract

A novel series of bio-based polyurethane composite foams was prepared, employing a cellulose-derived polyol for chain extension and cellulose-citrate as a thickener additive. The utilized polyol was obtained from the reduction reaction of cellulose-derived bio-oil through the use of sodium borohydride and iodine. Primarily, we produced both rigid and flexible polyurethane foams through chain extension of the prepolymers. Secondly, we investigated the role of cellulose citrate as a polyurethane additive to improve the mechanical properties of the realized composite materials. The products were characterized by FT-IR spectroscopy and their morphologies were analysed by SEM. Mechanical tests were evaluated to open new perspectives towards different applications.

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