WLTC and real-driving emissions for an autochthonous biofuel from wine-industry waste.

Residues from the wine industry constitute an abundant feedstock for biodiesel production in wine-producing countries. The use of grapeseed oil, together with bioethanol obtained from distillation of wine surplus or grape skins and stalks and wine lees, as reagents in the transesterification reaction, results in a mixture of fatty acid ethyl esters (FAEE), which is a fully renewable, autochthonous, and waste-derived biofuel. In this work, a blend of FAEE produced from grape seed oil with diesel fuel was selected based on a study of fuel properties, and the optimal blend, with 30% v/v of FAEE, was tested in a Euro 6 engine following the Worldwide harmonized Light-duty Test Cycle (WLTC) and a Real Driving Emissions Cycle (RDE), as required in the new certification procedures. Engine performance and emissions from this blend and a commercial diesel fuel were compared. The FAEE blend showed a significant potential to reduce particle emissions, both in mass and number (from 23% in number to 46.5% in mass for WLTC, and from 56% in number to 61% in mass for RDE), and CO (25.5% for WLTC and 39% for RDE) but penalized NOx (32% higher in WLTC and 26.4% higher in RDE).