Deactivation of 6-aminocoumarin intramolecular charge transfer excited state through hydrogen bonding

6-氨基香豆素分子内电荷转移激发态通过氢键失活

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作者:Ewa Krystkowiak, Krzysztof Dobek, Andrzej Maciejewski

Abstract

This paper presents results of the spectral (absorption and emission) and photophysical study of 6-aminocoumarin (6AC) in various aprotic hydrogen-bond forming solvents. It was established that solvent polarity as well as hydrogen-bonding ability influence solute properties. The hydrogen-bonding interactions between S1-electronic excited solute and solvent molecules were found to facilitate the nonradiative deactivation processes. The energy-gap dependence on radiationless deactivation in aprotic solvents was found to be similar to that in protic solvents.

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