The Schiff base ligand in the title compound, [Sn(C(4)H(9))(2)(C(11)H(12)ClNO(4))], chelates to the Sn atom through the two deprotonated O atoms, as well as through the N atom, to confer an overall cis-C(2)SnNO(2) trigonal-bipyramidal geometry at tin [C-Sn-C = 130.3â (1)°]. The hydr-oxy groups engage in O-Hâ¯O hydrogen bonding with the O atoms of adjacent mol-ecules, generating a chain running along the c axis.
(2-{[1,1-Bis(hydroxy-meth-yl)-2-oxidoeth-yl]imino-meth-yl}-4-chloro-phenolato-κN,O,O')dibutyl-tin(IV).
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作者:Reisi Reza, Misran Misni, Lo Kong Mun, Ng Seik Weng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Mar 31; 66(Pt 4):m482 |
| doi: | 10.1107/S1600536810011384 | ||
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