(4-Chloro-3-nitro-benzoato)triphenyl-tin(IV).

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作者:Win Yip-Foo, Choong Chen-Shang, Teoh Siang-Guan, Quah Ching Kheng, Fun Hoong-Kun
In the title compound, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))], the four-coordinate Sn(IV) atom exists in a distorted tetra-hedral geometry, formed by a monodentate carboxyl-ate group and three phenyl rings. The conformation is stabilized by an intra-molecular C-H⋯O hydrogen bond, which generates an S(5) ring. The aromatic ring of the 4-chloro-3-nitro-benzoate ligand makes dihedral angles of 75.64†(12), 64.37†(12) and 2.97†(12)° with the three phenyl ligands. The O atoms of the nitro group are disordered over two sets of sites in a 0.817†(5):0.183†(5) ratio. In the crystal, mol-ecules are linked via inter-molecular C-H⋯O hydrogen bonds into chains running parallel to [010].

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