The title compound, C(11)H(9)NO(3), contains an isoxazole and a hy-droxy-benzyl-idene ring, which are inclined to each another by 3.18â (8)°. There is an intra-molecular C-Hâ¯O contact forming an S(7) ring. In the crystal, mol-ecules stack head-to-tail in columns along the b-axis direction, linked by offset Ï-Ï inter-actions [inter-centroid distances of 3.676â (1) and 3.723â (1)â à ]. The columns are linked by O-Hâ¯O and O-Hâ¯N hydrogen bonds, forming layers parallel to the ab plane. The layers are linked by C-Hâ¯O hydrogen bonds, forming a supra-molecular three-dimensional framework. An analysis of the Hirshfeld surfaces points to the importance of the O-Hâ¯O and O-Hâ¯N hydrogen bonding in the packing mechanism of the crystal structure.
Crystal structure and Hirshfeld surface analysis of (Z)-4-(4-hy-droxy-benzyl-idene)-3-methyl-isoxazol-5(4H)-one.
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作者:Zemamouche Wissem, Laroun Rima, Hamdouni Noudjoud, Brihi Ouarda, Boudjada Ali, Debache Abdelmadjid
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2018 | 起止号: | 2018 Jun 8; 74(Pt 7):926-930 |
| doi: | 10.1107/S2056989018007867 | ||
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