In the structure of the title compound, C(19)H(19)N(3)O(5)S·C(4)H(8)O(2), the two independent dioxane mol-ecules each display inversion symmetry. The pyrazole ring is approximately parallel to the aromatic ring of the oxy-ethanone group and approximately perpendicular to the tolyl ring of the sulfonyl substituent. An extensive system of classical and 'weak' hydrogen bonds connects the residues to form a layer structure parallel to (201), within which dimeric subunits are conspicuous; neighbouring layers are connected by classical hydrogen bonds to dioxanes and by 'weak' hydrogen bonds from H(tol-yl) donors.
Crystal structure of 2-[(5-amino-1-tosyl-1H-pyrazol-3-yl)-oxy]-1-(4-meth-oxy-phen-yl)ethan-1-one 1,4-dioxane monosolvate.
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作者:Metwally Nadia H, Elgemeie Galal H, Jones Peter G
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2024 | 起止号: | 2024 Jan 1; 80(Pt 1):29-33 |
| doi: | 10.1107/S205698902301054X | ||
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