Effect of Molecular Weight and Degree of Substitution on the Physical-Chemical Properties of Methylcellulose-Starch Nanocrystal Nanocomposite Films.

This research studied the effect of molecular weight (M(w)) and degree of substitution (DS) on the microstructure and physicochemical characteristics of methylcellulose (MC) films with or without SNC. The M(w) and DS of three types of commercial MC (trade name of M20, A4C, and A4M, respectively) were in the range of 0.826 to 3.404 × 10(5) Da and 1.70 to 1.83, respectively. M(w) significantly affected the viscosity of methylcellulose solutions as well as the microstructure and tensile strength of methylcellulose films, while DS had a pronounced effect on their oxygen permeability properties. The incorporation of 15% (w/w) SNC resulted in the efficient improvement of tensile strength, water, and oxygen barrier properties of films, particularly for the A4C nanocomposite films. The results from SEM and FTIR illustrated that relatively homogenous dispersion of SNC was distinguished in A4C-15% (w/w) SNC films. Furthermore, microstructures of MC-SNC nanocomposite films were strongly dependent on both M(w) and DS of MC. This work offers a convenient and green method to fabricate MC-based nanocomposite films with desirable mechanical, light, oxygen, and water vapor barrier properties.