Crystal structure of a new 2,6-bis-(imino)-pyridine derivative: (1E,1'E)-1,1'-(pyridine-2,6-di-yl)bis-[N-(4-chloro-phen-yl)ethan-1-imine].

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作者:Rajesh Rajagopal, Sella E S, Blacque Olivier, Rajesh Kunjanpillai
The asymmetric unit of the title compound, C(21)H(17)Cl(2)N(3), contains two crystallographically independent mol-ecules (A and B). Both mol-ecules have E configurations for both imine double bonds with regard to the aryl and pyridine groups. The conformations of the two mol-ecules differ with the 4-chloro-phenyl rings being inclined to the central pyridine ring by 77.64†(6) and 86.18†(6)° in mol-ecule A, and 80.02†(5) and 43.41†(6)° in mol-ecule B. In the crystal, mol-ecules are linked by a number of C-H⋯π inter-actions, forming layers parallel to the bc plane.

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