The asymmetric unit of the title compound, C(21)H(17)Cl(2)N(3), contains two crystallographically independent mol-ecules (A and B). Both mol-ecules have E configurations for both imine double bonds with regard to the aryl and pyridine groups. The conformations of the two mol-ecules differ with the 4-chloro-phenyl rings being inclined to the central pyridine ring by 77.64â (6) and 86.18â (6)° in mol-ecule A, and 80.02â (5) and 43.41â (6)° in mol-ecule B. In the crystal, mol-ecules are linked by a number of C-Hâ¯Ï inter-actions, forming layers parallel to the bc plane.
Crystal structure of a new 2,6-bis-(imino)-pyridine derivative: (1E,1'E)-1,1'-(pyridine-2,6-di-yl)bis-[N-(4-chloro-phen-yl)ethan-1-imine].
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作者:Rajesh Rajagopal, Sella E S, Blacque Olivier, Rajesh Kunjanpillai
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2019 | 起止号: | 2019 Jan 4; 75(Pt 2):115-118 |
| doi: | 10.1107/S2056989018017966 | ||
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