The title mol-ecule, C(11)H(8)F(3)NO(3), adopts a cis configuration across the -C=C- double bond in the side chain and the dihedral angle between the phenyl ring and side chain is 47.35â (1)°. The -COOH group adopts a syn conformation (O=C-O-H = 0°), unlike the anti conformation observed in related maleamic acids. In the crystal, inversion dimers linked by pairs of O-Hâ¯O hydrogen bonds are connected via N-Hâ¯O hydrogen bonds and C-Hâ¯O inter-actions into (100) sheets, which are cross-linked by another C-Hâ¯O inter-action to result in a three-dimensional network. The Hirshfeld surface fingerprint plots show that the highest contribution to surface contacts arises from Oâ¯H/Hâ¯O contacts (26.5%) followed by Hâ¯F/Fâ¯H (23.4%) and Hâ¯H (17.3%).
N-[2-(Tri-fluoro-meth-yl)phen-yl]maleamic acid: crystal structure and Hirshfeld surface analysis.
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作者:Suchetan P A, Prakash Shet M, Lokanath N K, Naveen S, Warad Ismail
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2019 | 起止号: | 2019 May 10; 75(Pt 6):766-769 |
| doi: | 10.1107/S2056989019006509 | ||
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