In the title compound, C(26)H(32)BrClO(3), the dihedral angle between the 4-bromo-2-chloro-phenyl ring and the aromatic ring of (alk-yloxy)phenyl moiety is found to be 77.21â (2)°. The torsion angle associated with the ester moiety is 173.2â (2)° which is anti-periplanar. In the crystal, inter-molecular C-Hâ¯O hydrogen bonding links the mol-ecules into cyclic hydrogen-bonded inversion dimers with R (2) (2)(10) motifs. The mol-ecular structure is associated with an inversion centre and connected through two symmetrical C-Hâ¯O inter-actions, forming R (2) (2)(10) inversion dimer motif. The packing is further consolidated by C-Hâ¯Ï and C-Clâ¯Ï inter-actions. Hirshfeld surface analysis showed that the most significant contributions are from Hâ¯H (54.0%), Câ¯H/Hâ¯C (15.2%), Brâ¯H/Hâ¯Br (10.9%), Oâ¯H/Hâ¯O (7.8%) and Clâ¯H/Hâ¯Cl (2.6%) contacts.
Crystal structure and Hirshfeld surface analysis of 4-bromo-2-chloro-phenyl (E)-3-[4-(undec-yloxy)phen-yl]acrylate.
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作者:Devarajegowda H C, Palakshamurthy B S, Anil Kumar H, Srinivasa H T, Harish Kumar M
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2025 | 起止号: | 2025 Aug 15; 81(Pt 9):836-839 |
| doi: | 10.1107/S2056989025007078 | ||
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