Unraveling electronic origins for boosting thermoelectric performance of p-type (Bi,Sb)(2)Te(3).

P-type Bi(2-(x))Sb(x)Te(3) compounds are crucial for thermoelectric applications at room temperature, with Bi(0.5)Sb(1.5)Te(3) demonstrating superior performance, attributed to its maximum density-of-states effective mass (m*). However, the underlying electronic origin remains obscure, impeding further performance optimization. Herein, we synthesized high-quality Bi(2-(x))Sb(x)Te(3) (00 l) films and performed comprehensive angle-resolved photoemission spectroscopy (ARPES) measurements and band structure calculations to shed light on the electronic structures. ARPES results directly evidenced that the band convergence along the [Formula: see text]-[Formula: see text] direction contributes to the maximum m* of Bi(0.5)Sb(1.5)Te(3). Moreover, strategic manipulation of intrinsic defects optimized the hole density of Bi(0.5)Sb(1.5)Te(3), allowing the extra valence band along [Formula: see text]-[Formula: see text] to contribute to the electrical transport. The synergy of the above two aspects documented the electronic origins of the Bi(0.5)Sb(1.5)Te(3)'s superior performance that resulted in an extraordinary power factor of ~5.5 milliwatts per meter per square kelvin. The study offers valuable guidance for further performance optimization of p-type Bi(2-(x))Sb(x)Te(3).