The structure of the title compound, C(14)H(12)N(4)O(2), was determined as part of a project on the coordination chemistry of 1,2,4-triazole derivatives. In the crystal structure, one of the two benzene rings is almost coplanar with the five-membered triazole ring (mean deviation = 0.019â à ), whereas the second benzene ring is rotated by 51.973â (2)°. The two N-C-N-N torsion angles [170.365â (2) and -170.942â (3)°] indicate that the amido group is slightly twisted away from the triazole plane. An intra-molecular O-Hâ¯N hydrogen bond occurs. In the crystal structure, inter-molecular N-Hâ¯O and O-Hâ¯N hydrogen bonding is found.
2,2'-(4-Amino-4H-1,2,4-triazole-3,5-di-yl)diphenol.
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作者:Chen Sheng-Hui, Zhang Gao-Yong, Dong Jin-Feng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jan 9; 66(Pt 2):o330 |
| doi: | 10.1107/S1600536809055536 | ||
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