In the binuclear title complex, [Er(2)(C(13)H(9)N(3)O(2))(2)Cl(2)(CH(3)OH)(2)], the entire mol-ecule is generated by the application of inversion symmetry. Each Er(III) ion is seven-coordinated by two O atoms and one N atom from one N-(2-oxidobenzyl-idene)pyridine-2-carbohydrazidate (L(2-)) ligand, one O atom and one N atom from the symmetry-related L(2-) ligand, one O atom of a methanol mol-ecule and one chloride anion. The coordination geometry is based on a pseudo-penta-gonal bipyramid. Linear supra-molecular chains along [010] are formed in the crystal packing through O-Hâ¯Cl hydrogen bonds.
Bis[μ-N-(2-oxidobenzyl-idene)pyridine-2-carbohydrazidato]bis-[chlorido(methanol-κO)erbium(III)].
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作者:Yang, Hua
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 May 1; 68(Pt 5):m580-1 |
| doi: | 10.1107/S1600536812013979 | ||
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