The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the mol-ecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845â (2)â à , which is much longer than 3.2â à , the threshold for photoreactions to take place in the mol-ecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the mol-ecules are linked via weak inter-molecular C-Hâ¯O hydrogen bonds, forming a layer structure parallel to the ab plane.
Crystal structure of N-isopropyl-N-(phen-yl)phenyl-glyoxyl-amide.
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作者:Miyamoto Hisakazu, Yamauchi Genta, Ueno Takuya, Uekusa Hidehiro
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2018 | 起止号: | 2018 Oct 12; 74(Pt 11):1574-1576 |
| doi: | 10.1107/S2056989018013762 | ||
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