Crystal structure and Hirshfeld surface analysis of 4-bromo-6-phenyl-6,7-di-hydro-5H-furo[2,3-f]isoindol-5-one.

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作者:Alekseeva Kseniia A, Grigoriev Mikhail S, Kolesnik Irina A, Murshudlu Narmin A, Hasanov Khudayar I, Nazarova Roya Z, Akkurt Mehmet, Manahelohe Gizachew Mulugeta
The title mol-ecule, C(16)H(10)BrNO(2), is essentially planar (r.m.s. deviation = 0.004†à ). In the crystal, mol-ecules are linked by C-H⋯O and C-H⋯Br hydrogen bonds, forming ribbons along the b-axis direction. Furthermore, π-π inter-actions cause the mol-ecules to form ribbons along the [1 0 ] and [1 0 10] directions [centroid-to-centroid distances = 3.703†(3), 3.734†(3), 3.703†(3), and 3.734†(3)†à ]. According to a Hirshfeld surface analysis, H⋯H (33.8%), O⋯H/H⋯O (15.1%), C⋯H/H⋯C (14.6%), Br⋯H/H⋯Br (13.8%), and C⋯C (11.9%) inter-actions are the main contributors to the crystal packing.

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