In the title complex, [Ni(C(14)H(15)N(2)O(2))(2)], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898â (2) and 0.102â (2). The whole mol-ecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5â (2)°. The crystal packing is supported by C-Hâ¯Ï and C-Hâ¯O inter-actions that form a di-periodic layered network.
Crystal structure of bis-[4-(all-yloxy)-N'-(but-2-en-1-yl-idene)benzohydrazidato]nickel(II).
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作者:Khan Sultana Shakila, Howlader Md Belayet Hossain, Sheikh Md Chanmiya, Miyatake Ryuta, Zangrando Ennio
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2023 | 起止号: | 2023 Apr 14; 79(Pt 5):465-468 |
| doi: | 10.1107/S2056989023002918 | ||
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