The title compound, alternatively known as benzodi-aza-borole trimer, C(18)H(15)B(3)N(6)·2C(3)H(6)O, at 100â K crystallizes in the triclinic system, space group P . The structure displays N-Hâ¯O hydrogen bonding connecting the main mol-ecule with the crystallization solvent. Disorder of the main mol-ecule is observed with occupancy factors refined to 0.8922â (14):0.1078â (14). The packing of the crystal shows a parallel-displaced atom-centered orientation with 3.30â (2)â à between the planes of the rings. In the solid state, the title compound is linked with weak C-Hâ¯Ï inter-actions, which is supported by Hirshfeld surface analysis.
Crystal structure and Hirshfeld surface analysis of tri-aza-triborinotris[1,3,2]benzodi-aza-borole acetone disolvate.
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作者:Streeter Cole, Wheeler Kraig A, Lamm Ashley N
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2023 | 起止号: | 2023 Oct 31; 79(Pt 11):1104-1108 |
| doi: | 10.1107/S2056989023009337 | ||
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