In the title com-pound, C(30)H(20)Cl(2)O(2)Se, the C-Se-C angle is 99.0â (2)°, with the dihedral angle between the planes of the attached benzene rings being 79.1â (3)°. The average endocyclic angles (Se-C-C) facing the Se atom are 122.1â (5) and 122.2â (5)°. The Se atom is essentially coplanar with the attached benzene rings, deviating by 0.075â (1) and 0.091â (1)â à . In the two phenyl-ene(4-chloro-phen-yl)prop-2-en-1-one units, the benzene rings are inclined to each other by 44.6â (3) and 7.8â (3)°. In the crystal, the mol-ecules stack up the a axis, forming layers parallel to the ac plane. There are no significant classical inter-molecular inter-actions present. Hirshfeld surface analysis, two-dimensional fingerprint plots and the mol-ecular electrostatic potential surface were used to analyse the crystal packing. The Hirshfeld surface analysis suggests that the most significant contributions to the crystal packing are by Câ¯H/Hâ¯C contacts (17.7%).
Crystal structure and Hirshfeld surface analysis of (2E,2'E)-1,1'-[seleno-bis-(4,1-phenyl-ene)]bis-[3-(4-chloro-phen-yl)prop-2-en-1-one].
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作者:Bouraoui Hazem, Mechehoud Youcef, Chetioui Souheyla, Touzani Rachid, Medjani Meriem, Benmilat Ahmed, Boudjada Ali
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2019 | 起止号: | 2019 Oct 22; 75(Pt 11):1724-1728 |
| doi: | 10.1107/S2056989019014038 | ||
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