Synthesis, crystal structure and Hirshfeld surface analysis of 4-{(1E)-1-[(car-bamo-thioyl-amino)-imino]-eth-yl}phenyl propano-ate.

The title compound, C(12)H(15)N(3)O(2)S, adopts an E configuration with respect to the C=N bond. The propionate group adopts an anti-periplanar (ap) conformation. There are short intra-molecular N-H⋯N and C-H⋯O contacts, forming S(5) and S(6) ring motifs, respectively. In the crystal, mol-ecules are connected into ribbons extending parallel to [010] by pairs of N-H⋯S inter-actions, forming rings with R (2) (2)(8) graph-set motifs, and by pairs of C-H⋯S inter-actions, where rings with the graph-set motif R (2) (1)(7) are observed. The O atom of the carbonyl group is disordered over two positions, with a refined occupancy ratio of 0.27†(2):0.73†(2). The studied crystal consisted of two domains.