In the title compound, C(20)H(19)N(3)O(4), the dihedral angles between the central pyrazole ring and the pendant phenyl and substituted benzene rings are 50.95â (8) and 3.25â (12)°, respectively, and an intra-molecular C-Hâ¯O link generates an S(6) ring. The benzodioxolyl ring adopts a shallow envelope conformation with the methyl-ene C atom as the flap. In the crystal, the mol-ecules are linked by non-classical C-Hâ¯O inter-actions, which generate a three-dimensional network. Solvent-accessible voids run down the c-axis direction and the residual electron density in these voids was modelled during the refinement process using the SQUEEZE algorithm [Spek (2015 â¸). Acta Cryst. C71, 9-18] within the structural checking program PLATON.
Synthesis and structure of 4-{[(E)-(7-meth-oxy-1,3-benzodioxol-5-yl)methyl-idene]amino}-1,5-dimethyl-2-phenyl-2,3-di-hydro-1H-pyrazol-3-one.
阅读:8
作者:Arderne Charmaine, Fotsing Marthe Carine Djuide, Ndinteh Derek Tantoh
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2021 | 起止号: | 2021 Jan 29; 77(Pt 2):200-203 |
| doi: | 10.1107/S2056989021000797 | ||
特别声明
1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。
2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。
3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。
4、投稿及合作请联系:info@biocloudy.com。
