In the title compound, [NiFe(2)(C(5)H(5))(C(9)H(5)F(3)O(2))(2)(C(2)H(6)O)(2)], the central Ni(II) ion is observed in an octa-hedral coordination environment. The chelating β-diketonate ligands are substituted by ferrocene, a lipophilic organometallic moiety. The ferrocene groups have the normal geometry, with eclipsed cyclo-penta-diene rings. Coordinated ethanol mol-ecules are engaged in inter-molecular hydrogen bonds, and the crystal is further stabilized by weak C-Hâ¯F and C-Hâ¯Ï contacts.
Bis-(ethanol-κO)bis(1-ferrocenyl-4,4,4-tri-fluoro-butane-1,3-dionato-κ(2) O,O')nickel(II).
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作者:Su Wenqing, Fu Tianyue, Xu Zhongwei
| 期刊: | IUCrdata | 影响因子: | 0.000 |
| 时间: | 2021 | 起止号: | 2021 Jul 13; 6(Pt 7):x210693 |
| doi: | 10.1107/S2414314621006933 | ||
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