The asymmetric unit of the title compound, C(12)H(15)NO, comprises two sym-metry-independent mol-ecules which differ mainly in the conformations of the tert-butyl groups. The mol-ecules contain an essentially planar five-membered 3-pyrroline ring incorporating a carbonyl substituent (pyrrolinone) which forms part of an isoindolinone skeleton. The planarity of the pyrrole ring is compared to other structures with isoindolinone. There are only weak intra- and inter-molecular C-Hâ¯O and C-Hâ¯Ï-electron-ring inter-actions in the crystal structure.
Crystal structure of 2-tert-butyl-2,3-di-hydro-1H-benzo[c]pyrrol-1-one.
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作者:Donkeng Dazie Joel, LudvÃk JiÅÃ, Fábry Jan, Eigner Václav
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2017 | 起止号: | 2017 Jul 17; 73(Pt 8):1184-1188 |
| doi: | 10.1107/S2056989017010337 | ||
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