Quaternary tryptammonium salts: N,N-dimethyl-N-n-propyl-tryptammonium (DMPT) iodide and N-allyl-N,N-di-methyl-tryptammonium (DMALT) iodide.

The solid-state structures of two quaternary trytpammonium salts, namely, N,N-dimethyl-N-n-propyl-tryptammonium (DMPT) iodide [systematic name: 2-(1H-indol-3-yl)-N,N-dimethyl-N-propyl-aza-nium iodide], C(15)H(23)N(2) (+)·I(-), and N-allyl-N,N-di-methyl-tryptammonium (DMALT) iodide, [systematic name: 2-(1H-indol-3-yl)-N,N-dimethyl-N-(prop-2-en-1-yl)aza-nium iodide], C(15)H(21)N(2) (+)·I(-), are reported. Both salts possess a tri-alkyl-tryptammonium cation and an iodide anion in the asymmetric unit, which are joined together through N-H⋯I inter-actions. The DMALT structure was refined as an inversion twin, and the allyl group is disordered over two orientations with a 0.70†(4):0.30†(4) ratio.