In the title compound, [Ni(C(26)H(20)N(4)O(2))]·0.5C(4)H(10)O, the central metal ion is coordinated by four atoms of the tetra-dentate picolinamide ligand, forming a slightly distorted square-planar configuration, with an average Ni-N(pyridine) distance of 1.94â à and an average Ni-N(amide) distance of 1.83â à . The asymmetric unit contains one half-molecule of diethyl ether; this solvent molecule is disordered across a twofold rotation axis..
[N,N'-(1,2-Diphenyl-ethane-1,2-di-yl)bis-(pyridine-2-carboxamidato)]nickel(II) diethyl ether hemisolvate.
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作者:Yang Li, Deng Dong-Yan, Li Mei, Zhou Xiang-Ge
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2008 | 起止号: | 2008 Feb 6; 64(Pt 3):m439 |
| doi: | 10.1107/S1600536808002882 | ||
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