Crystal structure of tris-(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N')cobalt(III) tris-(hexa-fluoro-phosphate) monohydrate.

The title compound, [Co(C(72)H(48)N(6))](PF(6))(3)·H(2)O, crystallizes with one tripositive complex mol-ecule, three hexa-fluoro-phosphate anions and one solvent mol-ecule of water in the asymmetric unit. The N(6) coordination set around the central Co(III) atom defines a distorted octa-hedral environment. Four fluorine atoms of one hexa-fluoro-phosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697†(5) and 0.303†(5). In the crystal, inter-molecular π-π stacking inter-actions, C-H⋯π, C-H⋯F and O-H⋯F and inter-actions are present.