Crystal structure and Hirshfeld surface analysis of (3aSR,6RS,6aSR,7RS,11bSR,11cRS)-2,2-dibenzyl-2,3,6a,11c-tetra-hydro-1H,6H,7H-3a,6:7,11b-di-epoxy-dibenzo[de,h]isoquinolin-2-ium tri-fluoro-methane-sulfonate.

In the cation of the title salt, C(30)H(28)NO(2) (+)·CF(3)O(3)S(-), the four tetra-hydro-furan rings adopt envelope conformations. In the crystal, pairs of cations are linked by dimeric C-H⋯O hydrogen bonds, forming two R (2) (2)(6) ring motifs parallel to the (001) plane. The cations and anions are connected by further C-H⋯O hydrogen bonds, forming a three-dimensional network structure. Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H⋯H (47.6%), C⋯H/H⋯C (20.6%), O⋯H/H⋯O (18.0%) and F⋯H/H⋯F (9.9%) inter-actions.