The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent mol-ecules, both of which have the N,O-chelated Sn(IV) atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82â (8) and 137.69â (8)°]. The Cl atom of the mol-ecule with the smaller C-Sn-C angle inter-acts weakly with the Sn(IV) atom of the mol-ecule with the wider C-Sn-C angle at an Snâ¯Cl distance of 3.595â (1)â à . Weak inter-molecular C-Hâ¯O and C-Hâ¯Cl hydrogen bonding is present in the crystal structure.
Chloridometh-yl(2-methyl-quinolin-8-olato-κN,O)phenyl-tin(IV).
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作者:Vafaee Maryam, Amini Mostafa M, Ng Seik Weng
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 Jul 17; 66(Pt 8):m965 |
| doi: | 10.1107/S1600536810027790 | ||
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