The title compound, C(20)H(22)N(2)O(2), an alkaloid isolated from the Madagascar periwinkle, crystallizes in P1 with two independent but closely similar mol-ecules in the unit cell. The mol-ecules are linked into pairs by two N-Hâ¯O=C hydrogen bonds. The absolute configuration was confirmed by anomalous dispersion effects as S at the 3 and 15 positions, and R at the 7 position.
Crystal structure of akuammicine, an indole alkaloid from Catharanthus roseus.
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作者:Yahyazadeh Mahdi, Jerz Gerold, Selmar Dirk, Winterhalter Peter, Jones Peter G
| 期刊: | Acta Crystallographica Section E: Crystallographic Communications | 影响因子: | 0.500 |
| 时间: | 2017 | 起止号: | 2017 Oct 20; 73(Pt 11):1658-1661 |
| doi: | 10.1107/S2056989017014529 | ||
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