In the title compound, C(14)H(13)N(3)OS(2), the thio-phene ring is disordered over two orientations by ca 180° about the C-C bond axis linking the ring to the rest of the mol-ecule, with a site-occupancy ratio of 0.651â (5):0.349â (5). The central 1,3,4-oxadiazole-2(3H)-thione ring forms dihedral angles of 9.2â (5), 4.6â (11) and 47.70â (7)° with the major and minor parts of the disordered thio-phene ring and the terminal phenyl ring, respectively. In the crystal, no significant inter-molecular hydrogen bonds are observed. The crystal packing is stabilized by Ï-Ï inter-actions [centroid-centroid distance = 3.589â (2)â à ].
3-[(N-Methyl-anilino)meth-yl]-5-(thio-phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione.
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作者:El-Emam Ali A, Al-Omar Mohamed A, Ghabbour Hazem A, Fun Hoong-Kun, Chia Tze Shyang
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 May 1; 68(Pt 5):o1345-6 |
| doi: | 10.1107/S1600536812014419 | ||
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