Comparative Removal of Lead and Nickel Ions onto Nanofibrous Sheet of Activated Polyacrylonitrile in Batch Adsorption and Application of Conventional Kinetic and Isotherm Models.

We investigated the adsorption of lead (Pb(2+)) and nickel (Ni(2+)) ions by electrospun membranes of polyacrylonitrile (PAN) nanofiber activated with NaHCO(3) (PANmod). Analysis by Fourier-transform infrared spectrometry (FTIR), field emission scanning electron microscopy (FE-SEM), and energy dispersive X-ray spectroscopy (EDX) validated the functionalization of PAN nanofibers with NaHCO(3), and the successful agglomeration of Pb(2+) and Ni(2+) onto PANmod. After a rapid uptake of the heavy metal ions (15 min), the equilibrium contact time was attained (60 min) following a linear increase of both adsorption capacity and removal efficiency. PANmod showed a better affinity for Ni(2+) than Pb(2+). The adsorption on PANmod was best described by the pseudo-second-order kinetic model for both studied models, supporting chemisorption. By varying the solution pH from 2.0 to 9.0, we found that the adsorption capacity followed an increasing trend, reaching a maximum at the pH of 7.0. Despite increasing adsorption capacities, the removal efficiency of both heavy metal ions exhibited a decreasing trend with increase in initial concentrations. The amount of PANmod directly affects the removal efficiency, with 0.7 and 0.2 g being the optimum dose for maximum uptake of Pb(2+) and Ni(2+), respectively. The Langmuir model fitted well the Pb(2+) adsorption data suggesting monolayer adsorption, and the Freundlich model perfectly fitted the Ni(2+) adsorption data, indicating heterogeneous adsorption. The estimated values of the mean free energy of adsorption in the D-R isotherm indicated a physical adsorption of both heavy metal ions into the surface of the PANmod.