In the mol-ecule of title pyrazoline derivative, C17H18N4OS, the pyrazole ring adopts an envelope conformation with the flap atom, which bears the meth-oxy-phenyl substituent, displaced by 0.0750â (12)â à from the plane through the other ring atoms. The two substituted benzene rings make a dihedral angle of 70.59â (6)°. The meth-oxy group is twisted slightly with respect to the attached benzene ring [Cmeth-yl-O-C-C torsion angle = -8.84â (15)°]. An intra-molecular N-Hâ¯N hydrogen bond occurs. In the crystal, the pyrazoline mol-ecules are linked by N-Hâ¯O and N-Hâ¯S hydrogen bonds into zigzag layers parallel to the bc plane and stacked along the a axis by Ï-Ï inter-actions with centroid-centroid distances of 3.4690â (7) and 3.5792â (7)â à . C-Hâ¯Ï inter-actions are also present.
3-(4-Amino-phen-yl)-5-(4-meth-oxy-phen-yl)-4,5-di-hydro-1H-pyrazole-1-carbo-thio-amide.
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作者:Suwunwong Thitipone, Chantrapromma Suchada, Chidan Kumar C S, Fun Hoong-Kun
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2013 | 起止号: | 2013 Jul 10; 69(Pt 8):o1227-8 |
| doi: | 10.1107/S1600536813018096 | ||
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