In the structure of the title coordination polymer, [K(C(8)H(5)N(2)O(6))](n), each ligand bridges six K(+) cations. The carboxyl-ate group coordinates both bidentately to one K(+) ion and monodentately to two K(+) ions, while one nitro group coordinates bidentately to a fourth K(+) ion. The last two K(+) ions are coordinated by the remaining nitro group, one in a bidentate fashion, the other monodentately through one O atom. This bridging mode results in a three-dimensional network. The coordination geometry of the K(+) ion is represented by an irregular KO(9) polyhedron. Very weak C-Hâ¯O inter-actions are observed in the crystal structure.
Poly[(μ(6)-2-methyl-3,5-dinitro-benzoato)potassium].
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作者:Danish Muhammad, Saleem Iram, Ahmad Nazir, Starosta Wojciech, Leciejewicz Janusz
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2010 | 起止号: | 2010 May 8; 66(Pt 6):m616 |
| doi: | 10.1107/S1600536810015400 | ||
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