The title compound, C(24)H(29)NO(7), is asymmetric with a chiral centre located in the pyran ring and crystallizes as a racemate. The coumarin ring system and the fused pyran ring make a dihedral angle of 10.46â (8)°. A short intra-molecular N-Hâ¯O hydrogen bond between the amino group and the vicinal carbonyl group generates an S(6) ring. Inter-molecular C-Hâ¯O inter-actions contribute to the stability of the crystal structure.
rac-Dimethyl 5-oxo-2-[(2,4,4-trimethyl-pentan-2-yl)amino]-4,5-dihydro-pyrano[3,2-c]chromene-3,4-dicarboxyl-ate.
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作者:Inglebert S Antony, Arun Yuvaraj, Sethusankar K, Perumal Paramasivam T
| 期刊: | Acta Crystallographica Section E-Structure Reports Online | 影响因子: | 0.600 |
| 时间: | 2012 | 起止号: | 2012 Jul 1; 68(Pt 7):o2177 |
| doi: | 10.1107/S1600536812027596 | ||
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